瑜氬畯鎬★紝椴侀噾鍑ゃ€佸瘒鏂硅埅锛岄練妤氭灚锛屾娑涳紝闃垮厠姹?br /> (1.鍗楀紑澶у鐜绉戝涓庡伐绋嬪闄紝澶╂触300071;2锛岀幆澧冩薄鏌撹繃绋嬩笌鍩哄噯鏁欒偛閮ㄩ噸鐐瑰疄楠屽(鍗楀紑澶у)锛屽ぉ娲?000713.榛戦緳姹熷伐绋嬪闄㈠湡鏈ㄤ笌寤虹瓚宸ョ▼瀛﹂櫌锛岄粦榫欐睙鍝堝皵婊?50050)
鎽樿锛氳繃纭吀鐩愰珮绾ф哀鍖栨妧鏈湪姘村鐞嗘柟闈㈡湁鐫€鍗佸垎骞块様鐨勫簲鐢ㄥ墠鏅紝瀹冭兘閫氳繃娲诲寲浜у己姘у寲鎬х殑纭吀鏍硅嚜鐢卞熀锛屽叾瀵瑰簾姘翠腑鐨勯毦闄嶈в鏈夋満鐗╁叿鏈夋瀬寮虹殑姘у寲鑳藉姏锛屼粙缁嶄簡鍥藉唴澶栧湪澹~閰哥洂娲诲寲鎶€鏈柟闈㈢殑杈冩柊鐮旂┒杩涘睍锛屽寘鎷儹銆佸厜銆佽繃娓¢噾灞炵瓑澶氱娲诲寲鏂瑰紡锛屽苟鎬荤粨浜嗚繃纭吀鐩愪簯鍖栨妧鏈殑鍙戝睍鏂瑰悜銆?
闅忕潃宸ヤ笟鐨勯珮閫熷彂灞曪紝搴熸按鐨勪骇閲忎笌鏃ヤ勘澧烇紝搴熸按涓湁鏈虹墿鐨勬垚鍒嗕篃鎰堝姞澶嶆潅锛屼紶缁熷簾姘村鐞嗘柟娉曞凡缁忛毦浠ユ弧瓒虫棩鐩婁弗鏍肩殑鎺掓斁鏍囧噯銆傜壒鍒槸搴熸按涓竴浜涢珮绋冲畾鎬с€侀毦闄嶈в鐨勬湁鏈烘薄鏌撶墿锛岀敱浜庡叾鐢熷寲鎬у樊锛屼紶缁熺殑鐢熺墿澶勭悊鎶€鏈鍏剁殑澶勭悊鏁堟灉寰堝樊锛屽洜姝ら渶瑕佸湪鐢熺墿澶勭悊宸ヨ壓涔嬪墠璁剧疆鑳藉皢闅鹃檷瑙f湁鏈虹墿杞寲涓烘槗鐢熺墿闄嶈в鐨勫皬鍒嗗瓙鏈夋満鐗╃殑楂樼骇姘у寲宸ヨ壓銆?
楂樼骇姘у寲鎶€鏈槸涓€绉嶄績杩涗骇鐢熻嚜鐢卞熀鐨勬哀鍖栨妧鏈紝杈冩棭鐨勯珮绾ф哀鍖栨妧鏈兘鏃ㄥ湪淇冭繘浜х敓缇熷熀鑷敱鍩?路oh)锛屄稯h鐨勬哀鍖栬繕鍘熺數浣嶄负2.8v,楂樹簬鑷哀鐨勬哀鍖栬繕鍘熺數浣嶏紝瀵规湁鏈虹墿鐨勬哀鍖栨棤閫夋嫨鎬с€傚綋鍓嶏紝姹℃按澶勭悊涓父鐢ㄧ殑楂樼骇姘у寲鎶€鏈湁鑺】娉曘€佺被鑺】娉曘€佹箍寮忔哀鍖栨硶銆佽繃纭吀鐩愭硶绛夈€傝繃纭吀鐩愰珮绾ф哀鍖栨妧鏈槸涓€绉嶆柊鍏寸殑閫氳繃娲诲寲杩囩~閰哥洂浜х敓路s04-,浠ヨ瑙f按涓湁鏈虹墿鐨勯珮绾ф哀鍖栨妧鏈€備笌路oh鐩告瘮锛屄穝04-鍏锋湁鍙梡h褰卞搷鑼冨洿灏忋€侀€夋嫨鎬у己绛変紭鐐癸紝鏈夋晥閬垮厤浜嗕紶缁熼珮绾ф哀鍖栨妧鏈殑缂洪櫡锛屾棩鐩婂彈鍒伴潚鐫愩€傝€岃繃纭吀鐩愰珮绾ф哀鍖栨妧鏈鍙戞尌鍏跺己姘у寲鎬э紝闇€瑕佸€熷姪娲诲寲鎶€鏈縺鍙戣繃纭吀鐩愪骇鐢熉穝04-锛屽父鐢ㄧ殑娲诲寲鏂规硶涓昏鍖呮嫭鐑椿鍖栨硶銆佸厜娲诲寲娉曘€佽繃娓¢噾灞炲偓鍖栧墏娲诲寲娉曠瓑銆?br /> 1 鐑椿鍖?br /> 鐑椿鍖栨槸鍦ㄧ儹鎴栧姞鐑殑浣滅敤涓嬶紝浣胯繃纭吀鏍逛腑鐨勫弻姘ч敭鏂锛屼骇鐢熷己姘у寲鎬х殑纭吀鏍硅嚜鐢卞熀銆傜儹娲诲寲鎵€闇€鐨勮兘閲忕害涓?40.02kj/mol.鐑椿鍖栬繃纭吀鐩愭妧鏈湪鍦熷¥淇銆佸簾姘村鐞嗗拰鍦颁笅姘翠慨澶嶆柟闈㈠緱鍒颁簡骞挎硾鐨勫簲鐢紝鍦ㄧ儹娲诲寲鐨勬柟寮忎腑锛屾俯搴﹀姹℃煋鐗╃殑鍒嗚в璧峰埌浜嗗叧閿殑浣滅敤銆傜爺绌朵腑鍙戠幇锛屾彁楂樻俯搴﹀彲鍔犲揩鐑椿鍖栨妧鏈殑鏁堢巼銆侸iyf绛?鍦ㄧ儹娲诲寲杩囩~閰哥洂闄嶈в闃跨壒鎷夋触鏃跺彂鐜帮紝闃跨壒鎷夋触鐨勯檷瑙g鍚堜竴绾у弽搴斿姩鍔涘妯″瀷銆傚綋娓╁害涓?0锝?0鈩冩椂闃跨壒鎷夋触鐨勯檷瑙f晥鐜囨槑鏄鹃殢鐫€娓╁害鐨勫崌楂樿€屽澶э紝褰撴俯搴︿粠30鈩冨彉鍖栬嚦60鑹烘椂锛岄€熺巼甯告暟澧炲ぇ浜?14鍊嶃€備絾骞堕潪瀵逛簬鎵€鏈夋薄鏌撶墿锛屾俯搴﹁秺楂橀檷瑙f晥鐜囪秺濂姐€傚紶钀嶈悕绛夊彂鐜扮儹娲诲寲杩囩~閰哥洂闄嶈в鑱旇嫰鑳猴紝娓╁害涓?0鈩冩椂鐨勯檷瑙f晥鏋滃弽鑰岄珮浜?0鈩冩椂銆傜殑娲绘€у緢楂橈紝瀛樺湪鏃堕棿寰堢煭锛岄儴鍒喡穝04-鍦ㄦ湭寰楀埌鍏呭垎鍒╃敤涔嬪墠渚胯闄嶈в銆傚洜姝わ紝鍦ㄧ儹娲诲寲杩囩~閰哥洂鏃惰娉ㄦ剰閫夋嫨浣虫椿鍖栨俯搴︺€傝繖鍙兘鏄洜涓哄綋娓╁害杩囬珮鏃讹紝路s04-鐨勬椿鎬у緢楂橈紝瀛樺湪鏃堕棿寰堢煭锛岄儴鍒喡稴04鍦ㄦ湭寰楀埌鍏呭垎鍒╃敤涔嬪墠渚胯闄嶈в銆傛椂瑕佹敞鎰忛€夋嫨浣虫椿鍖栨俯搴︺€?
鐑椿鍖栬繃纭吀鐩愰珮绾ф哀鍖栨妧鏈姘翠腑鐨勪竴浜涘啘鑽€佺幆澧冩縺绱犮€佽嵂鐗╁強涓汉鎶ょ悊鍝?ppcps)绛夐兘鏈夎緝楂樼殑闄嶈в鏁堣兘銆俆an c q鍙戠幇锛屽湪閰告€с€佹棤婧惰в鏈夋満璐ㄧ殑鏉′欢涓嬶紝鐑椿鍖栬繃纭吀鐩愯兘鏈夋晥闄嶈в鑽墿瀹夋浛姣旀灄銆傛牼娴峰浆""鐨勭爺绌惰〃鏄庣儹娲诲寲鍦?0鈩冧笅鍙嶅簲60min锛屽鍙岄厷a鍜屽,鍩洪厷鐨勯檷瑙g巼鍒嗗埆杈惧埌浜?8.5%鍜?4.8%銆傜儹娲诲寲杩囩▼闄や簡鍙楀簳鐗╂祿搴︺€佹俯搴﹀奖鍝嶅锛宲h.婧舵恫涓殑鏃犳満闃寸瀛愩€佸ぉ鐒舵湁鏈虹墿涔熶細褰卞搷鐑椿鍖栬繃纭吀鐩愰檷瑙f湁鏈虹墿鐨勬晥鑳姐€傚湪闄嶈в鍙岄厷f鐨勯檷瑙g▼搴﹁楂樹簬涓€у拰纰辨€ф潯浠朵笅锛岄€氬父閰告€ф潯浠朵笅鐑椿鍖栬繃纭吀鐩愭妧鏈鏈夋満鐗╃殑闄嶈в鏁堣兘鏇撮珮銆傚疄楠岃繕鍙戠幇锛屾憾娑蹭腑鏃犳満闃寸瀛愬拰澶╃劧鏈夋満鐗╃殑瀛樺湪閮戒細鍦ㄤ竴瀹氱▼搴︿笂鎶戝埗鐑椿鍖栬繃纭吀鐩愬鏈夋満鐗╃殑闄嶈в鏁堣兘锛屽浜庝笉鍚岀殑鏈夋満鐗╋紝闃寸瀛愮殑鎶戝埗绋嬪害涓嶅悓銆傝繖鍙兘鏄敱浜庢煇浜涙棤鏈洪槾绂诲瓙浼氱対鐏洜姝わ紝鍦ㄧ儹娲诲寲杩囩~閰哥洂a鐨勫疄楠屼腑鍙戠幇锛岄€氬父閰告€ф潯浠朵笅鐑椿鍖栬繃纭吀鐩愭妧鏈鏈夋満鐗╃殑闄嶈в鏁堣兘鏇撮珮銆傚疄楠岃繕鍙戠幇锛屾憾娑蹭腑鏃犳満闃寸瀛愬拰澶╃劧鏈夋満鐗╃殑瀛樺湪閮戒細鍦ㄤ竴瀹氱▼搴︿笂鎶戝埗鐑椿鍖栬繃纭吀鐩愬鏈夋満鐗╃殑闄嶈в鏁堣兘锛屽浜庝笉鍚岀殑鏈夋満鐗╋紝闃寸瀛愮殑鎶戝埗绋嬪害涓嶅悓"]銆傝繖鍙兘鏄敱浜庢煇浜涙棤鏈洪槾绂诲瓙浼氱対鐏稴04锛岃€岀対鐏▼搴︿笌鏈夋満鐗╁拰闃寸瀛愪簤澶鸿嚜鐢卞熀鐨勯€熺巼鏈夊叧鍚屾牱锛屽ぉ鐒舵湁鏈虹墿浣滀负闅鹃檷瑙g殑澶у垎瀛愬ぉ鐒剁墿璐紝涔熶細鍜屽叾浠栫洰鏍囨湁鏈虹墿浜夊ず鑷敱鍩哄拰姘у寲鍓傦紝浣跨洰鏍囨湁鏈虹墿鐨勯檷瑙f晥鐜囦笅闄嶃€傚苟闈炴墍鏈夌殑鏃犳満闃寸瀛愰兘浼氭姂鍒舵湁鏈虹墿鐨勯檷瑙c€傚粬浜戠嚂鍦ㄩ檷瑙i樋鐗规媺娲ョ殑瀹為獙涓彂鐜帮紝娴撳害涓?0mmo浼奓浠ヤ笅鐨凜1-鑳藉姞閫熼樋鐗规媺娲ョ殑鍘婚櫎锛岃繖鍙兘鏄洜涓篊i-浼氫笌路so.鍙嶅簲鐢熸垚c1.锛孋l銆備篃鍏锋湁寰堝己鐨勬哀鍖栬兘鍔涳紝浠庤€屾哀鍖栭檷瑙i樋鐗规媺娲ヤ絾鏄綋c1-鐨勬祿搴﹂珮浜?0mmol/l鍚庯紝闃跨壒鎷夋触鐨勯檷瑙g巼灏嗕細闄嶄綆锛屽師鍥犳槸c1路浼氫笌杩囬噺鐨凜1锛屽弽搴旂敓鎴怌i.'锛岃€孋1.路鐨勬哀鍖栬兘鍔涚浉瀵逛簬c1路鍜屄稴o.杈冨急锛岄樋鐗规媺娲ョ殑鍘婚櫎鐜囦細蹇€熼檷浣庛€傚洜姝わ紝鏃犳満闃寸瀛愬搴曠墿鐨勯檷瑙f墍璧峰埌鐨勪綔鐢ㄦ槸涓嶄竴瀹氱殑銆傛潕鏃紵绛?'涔熷緱鍒颁簡鐩镐技鐨勭粨璁猴紝鍦ㄩ檷瑙f按涓瘨姝昏湵鐨勫疄楠屼腑锛孋1-鍦ㄤ竴瀹氱▼搴︿笂鑳戒績杩涙瘨姝昏湵鐨勯檷瑙o紝鑰孋o-鍜孒co,浼氭姂鍒堕檷瑙i€熺巼锛孲o-瀵归檷瑙f棤褰卞搷銆?br /> 闄や簡甯歌鐨勭數鍔犵儹娲诲寲娉曞锛岀儹娲诲寲杩樻湁寰尝鍔犵儹娲诲寲鐨勬柟寮忋€傚井娉㈡椿鍖栨墍闇€鐨勫弽搴旀椿鍖栬兘鏇翠綆锛屽弽搴旀椂闂存洿鐭紝鑳藉揩閫熶负鍙嶅簲鎻愪緵鎵€闇€鐨勮兘閲忋€俌ang s y鍙戠幇锛屽井娉㈣兘鏈夋晥娲诲寲杩囩~閰哥洂浠庤€屾湁鏁堥檷瑙e伓姘煋鏂橝07锛屼娇a07鍦?锝?min鍐呭畬鍏ㄨ劚鑹层€傜鎵块兘绛夊埄鐢ㄥ井娉㈠姞鐑椿鍖栫殑鏂瑰紡娲诲寲杩囩~閰哥洂闄嶈в浜旀隘閰氭寔涔呮€ф湁鏈虹墿锛岀粨鏋滆〃鏄庯紝浠呯敤寰尝澶勭悊鎴栬€呬粎鍔犲叆杩囩~閰搁捑鏃讹紝浜旀隘閰氬嚑涔庡緱涓嶅埌闄嶈в锛岃€屼袱鑰呭潎瀛樺湪鐨勬潯浠朵笅锛?0min鍗冲彲杈惧埌瀵逛簲姘厷99%鐨勫幓闄ょ巼璋冩暣鍙嶅簲鐗╃殑姣斾緥锛?4min鍗冲彲瀹屽叏鐭垮寲锛屼笌鐢电儹鍔犵儹娉曠浉姣旀瀬澶у湴鎻愰珮浜嗘椿鎬ф晥鑳姐€傜敱姝ゅ彲瑙侊紝寰尝鍔犵儹鏄竴绉嶆洿鐨勬椿鍖栨柟娉曘€?
鏃犺鏄數鐑椿鍖栬繕鏄井娉㈠姞鐑椿鍖栵紝鍦ㄥ弽搴旇繃绋嬩腑閮戒細浜х敓纭吀鏍硅嚜鐢卞熀鍜岀緹鍩鸿嚜鐢卞熀'"1锛岃繖浜涘己姘у寲鎬х殑鑷敱鍩鸿兘灏嗘薄鏌撶墿蹇€熷幓闄ゃ€傚洜姝わ紝鏈潵搴旀帰绌跺浣曚娇鐑椿鍖栨洿蹇湴浜х敓鑷敱鍩猴紝鎻愰珮姘у寲鏁堣兘銆?
2鍏夋椿鍖?br /> 鍏夋椿鍖栨槸閲囩敤绱鍏夈€佹棩鍏夌瓑鍏夎兘娲诲寲锛屼笌鐑椿鍖栫浉浼硷紝閫氳繃鎵€浼犻€掔殑鑳介噺浣垮弻姘ч敭鏂锛屽湪瀹ゆ俯涓嬩究鑳戒骇鐢熺~閰告牴鑷敱鍩虹殑涓€绉嶈繃纭吀鐩愭椿鍖栨柟娉曘€侺i s绛夊姣斾簡鍗曠嫭uv.鍗曠嫭ps鍜孶v/ps浣撶郴涓嬪鐩爣鐗╃殑鍘婚櫎鏁堟灉锛屽彂鐜癠v/ps浣撶郴涓嬶紝鐩爣搴曠墿鐨勫幓闄ゆ晥鐜囪兘澶熷ぇ骞呭害鎻愰珮锛岀敱姝ゅ彲瑙乁v鑳藉鏈夋晥娲诲寲ps.褰卞搷娲诲寲鏁堢巼鐨勪富瑕佸洜绱犱负娉㈤暱鍜岀┛閫忛€熺巼l14j閫傚疁鐨勬尝闀垮拰杈冨揩鐨勭┛閫忛€熺巼鑳戒娇鍙嶅簲杩囩▼涓骇鐢熸洿澶氱殑纭吀鏍瑰悜鐢卞熀锛屽揩閫熸彁楂樻哀鍖栨晥鑳姐€侼eppolian绛夌爺绌跺彂鐜帮紝娉㈤暱涓?54nn1鐨勭传澶栧厜鑳芥湁鏁堟椿鍖栬繃纭吀鐩愶紝鑰岃兘閲忚緪灏勪綆鐨勫厜婵€娲昏繃纭吀鐩愮殑鑳藉姏鐩稿杈冨急銆侺inyt绛夊湪娓╁害涓?5鍦?鑹虹殑鐜涓敤254nm鐨勭传澶栧厜娲诲寲杩囩~閰搁挔澶勭悊鑻厷锛屽綋杩囩~閰哥洂娴撳害涓?4mmol/l銆佽嫰閰氬垵濮嬫祿搴︿负0.5mmo1/l鏃讹紝鍙嶅簲20min渚胯兘蹇€熷畬鍏ㄥ湴闄嶈в鑻厷锛孏aoyq绛夌敤绱鍏夋椿鍖栬繃纭吀鐩愬幓闄ゆ按涓殑纾鸿兒鐢插槯鍟舵椂鍙戠幇锛岀传澶栧厜杩囩~閰哥洂鏄竴绉嶅彲琛岀殑鍘婚櫎姘翠腑纾鸿兒鐢插槯鍟剁殑鏂规硶锛孌hakasarita绛夌敤绱鍏夋椿鍖栬繃纭吀鐩愰檷瑙h嫰鐢查吀鐢查叝锛?0min鍐呰嫰鐢查吀鐢查叝鐨勯檷瑙g巼鑳借揪鍒?8.9%锛屽湪鍙嶅簲杩囩▼涓悓鏃跺瓨鍦稴o.鍜屄稯h,ph鎺ヨ繎涓€ф椂锛屄稴o.涓轰富瑕佺殑鑷敱鍩恒€傜传澶栧厜娲诲寲杩囩~閰哥洂鐨勯珮绾ф哀鍖栨妧鏈篃甯歌鐢ㄤ綔闄嶈в鎶楃敓绱爉-201銆佸叏姘熻緵閰?'绛夊浜轰綋瀛樺湪娼滃湪鏆撮湶椋庨櫓鐨勭墿璐ㄣ€傝櫧鐒跺崟鐙琔v.鍗曠嫭ps渚胯兘闄嶈в涓€閮ㄥ垎鎶楃敓绱犲姘湁绱犮€侀噾闇夌礌绛夋垨鍏ㄦ盁杈涢吀锛屼絾涓よ€呰仈鍚堜娇鐢ㄤ細澶уぇ鎻愰珮瀵规姉鐢熺礌銆佸叏姘熻緵閰哥殑闄嶈в鏁堣兘銆傜传澶栬兘鏈夋晥鍦版椿鍖栬繃纭吀鐩愶紝浣嗗簲鐢ㄤ簬瀹為檯鍗村叿鏈変竴瀹氱殑灞€闄愭€х传澶栨椿鍖栧璁惧鐨勮姹傝仢楂橈紝鏃犲舰涓鍔犱簡鎴愭湰涓庣儹娲诲寲鐩告瘮锛岀传澶栨椿鍖栫~閰哥洂瀵归毦闄嶈в鏈夋満鐗╃殑闄嶈в鏁堣兘杈冧綆锛屽挨鍏剁敤杈冮珮鑹插害鍜岄€忓厜鐜囪緝浣庣殑搴熸按銆?br /> 3.杩囨浮閲戝睘鍌寲鍓傛椿鍖?br /> 杩囨浮閲戝睘鍌寲鍓傛椿鍖栨槸閫氳繃鎶曞姞鍌寲鍓傜殑鏂瑰紡锛屼績杩涜繃纭吀鐩愪骇鐢熉稴04銆傝繃娓¢噾灞炴椿鍖栨搷浣滅畝鍗曪紝鏃犻渶澶栧姞鐑簮鍜屽厜婧愶紝澶уぇ鑺傜害浜嗘垚鏈€傛牴鎹姇鍔犵殑鍌寲鍓傜殑褰㈠紡锛岃繃娓¢噾灞炲偓鍖栧墏娲诲寲鍙堝垎涓哄潎鐩稿偓鍖栨椿鍖栨硶鍜岄潪鍧囩浉鍌寲娲诲寲娉曚袱绉嶃€傚潎鐩稿嵆閲囩敤涓€浜涜繃娓¢噾灞炵瀛愪綔涓哄偓鍖栧墏娲诲寲杩囩~閰哥洂锛岃€岄潪鍧囩浉涓洪噰鐢ㄤ竴浜涘浐浣撻噾灞炲強閲戝睘姘у寲鐗╀綔涓哄偓杩囨浮閲戝睘鍌寲鍓傛椿鍖栨槸閫氳繃鎶曞姞鍌寲鍓傜殑鏂瑰紡锛屼績杩涜繃纭吀鐩愪骇鐢熉稴04銆傝繃娓¢噾灞炴椿鍖栨搷浣滅畝鍗曪紝鏃犻渶澶栧姞鐑簮鍜屽厜婧愶紝澶уぇ鑺傜害浜嗘垚鏈€傛牴鎹姇鍔犵殑鍌寲鍓傜殑褰㈠紡锛岃繃娓¢噾灞炲偓鍖栧墏娲诲寲鍙堝垎涓哄潎鐩稿偓鍖栨椿鍖栨硶鍜岄潪鍧囩浉鍌寲娲诲寲娉曚袱绉嶃€傚潎鐩稿嵆閲囩敤涓€浜涜繃娓¢噾灞炵瀛愪綔涓哄偓鍖栧墏娲诲寲杩囩~閰哥洂锛岃€岄潪鍧囩浉涓洪噰鐢ㄤ竴浜涘浐浣撻噾灞炲強閲戝睘姘у寲鐗╀綔涓哄偓鍖栧墏鎶曞叆杩囩~閰哥洂浣撶郴锛岃繘琛屾椿鍖栥€?br /> 杩囨浮閲戝睘绂诲瓙娲诲寲杩囩~閰哥洂浜х敓寮烘哀鍖栨€х殑纭吀鏍硅嚜鐢卞熀鐨勫弽搴旀柟绋嬪紡涓篗n s2o82- 鈫扢锛坣 1锛? 路so4- so42-銆傝繃娓¢噾灞炵瀛愬fe2'銆丮n2 銆丆u2 銆丆o2*鍦ㄥ父娓╀笅鍗冲彲娲诲寲杩囩~閰哥洂浜х敓纭吀鏍硅嚜鐢卞熀锛屽姘翠腑鐨勬薄鏌撶墿鍏锋湁鑹ソ鐨勯檷瑙f晥鏋溿€傚瓩濞佺瓑鍦ㄦ瘮杈冧笉鍚岃繃娓¢噾灞炴椿鍖栬繃纭吀鐩愰檷瑙g敳鍩烘鏌撴枡搴熸按鐨勫疄楠屼腑鍙戠幇锛屽湪閲戝睘绂诲瓙鎶曞姞閲忕浉鍚岀殑鏉′欢涓嬶紝fe2 鐨勬椿鍖栨晥鏋滃ソ銆侳e2 鏄父鐢ㄧ殑娲诲寲杩囩~閰哥洂鐨勯噾灞炵瀛愶紝鍙嶅簲杩呴€燂紝浠锋牸渚垮疁锛岀幆澧冨弸濂斤紝鍌寲鏁堢巼楂樸€備絾fe2 鍚屾椂鏄~閰告牴鑷敱鍩虹殑鎹曟崏鍓傦紝褰撴憾娑蹭腑fe2 杩囬噺鏃讹紝fe 2 浼氫笌路so.鍙嶅簲浣挎哀鍖栨晥鑳介檷浣?4銆戯紝涓斿弽搴斾腑鏄撳舰鎴愬ぇ閲忛搧娉ワ紝婧舵恫涓璅e 2 鐨勫悗缁鐞嗕篃杈冧负楹荤儲锛屽洜姝ゆ彁鍑轰娇鐢ㄩ浂浠烽搧鏉ョ紦閲奆e 2 銆?br /> 鍦ㄧ洰鍓嶇殑鐮旂┒涓紝闆朵环閾佹槸闈炲潎鐩稿偓鍖栨椿鍖栬繃纭吀鐩愪綋绯讳腑闈炲父鐑棬鐨勬椿鍖栧墏銆侽h sy绛?j鍦ㄧ敤闆朵环閾佸偓鍖栬繃纭吀鐩愰檷瑙?,4-浜岀鍩虹敳鑻?dnt)鐨勫疄楠屼腑鍙戠幇锛屽綋fe o/s,0-浣撶郴涓璂nt琚畬鍏ㄩ檷瑙f椂锛屽湪fe2'/s,0-浣撶郴涓粎鏈変笉鍒?0%鐨凞nt琚檷瑙o紝鍙feo鏄洿鏈夋晥鐨勬椿鍖栧墏锛岃敗娑涚瓑"6鍚屾牱寰楀嚭feo鏄洿涓烘湁鏁堢殑娲诲寲鍓傜殑璁哄湪闆朵环閾佹椿鍖栬繃浜岀~閰哥洂姘у寲闄嶈в闃跨壒鎷夋触鐨勫疄楠屼腑鍙戠幇锛屽綋鍒濆ph涓?.5.1 ml pds鐨勫垵濮嬫祿搴︿负2mmo1/l.fe o鎶曞姞閲忎负28 m鍚曠殑鏉′欢涓嬶紝鍙嶅簲60min鍚嶧e o/pds浣撶郴瀵?00ml娴撳害涓?.1mmovl闃跨壒鎷夋触鐨勯檷瑙g巼杈惧埌w.o%锛岃繙楂樹簬fez'/pds鍜孎e3'/pds浣撶郴瀵归樋鐗规媺娲ョ殑闄嶈в鐜囥€傚垬鏅楃瓑"7鍦ㄧ传澶栧厜鍗忓姪闆朵环閾佹椿鍖栬繃纭吀鐩愰檷瑙e叏姘熻緵鐑风:閰哥洂鐨勫疄楠屼腑鍙戠幇锛屽崟鐙噰鐢ㄧ传澶栧厜娲诲寲杩囩~閰哥洂锛屽弽搴?4h鍚庡簳鐗╃殑鍘婚櫎鐜囦笉鍒?0%鍔犱汉閾佺矇鍚庯紝闆朵环閾佸拰绱鍏夊叡鍚屾縺娲昏繃纭吀鐩愶紝鍏ㄦ盁杈涚兎纾洪吀鐩愮殑闄嶈в鏁堟灉鏄庢樉澧炲姞锛屽弽搴?4h鍚庨檷瑙g巼杈惧埌91%銆傜敱姝ゅ彲瑙侊紝闆朵环閾佸叿鏈夊緢濂界殑娲诲寲鏁堟灉銆傜洰鍓嶏紝鍦ㄩ€夋嫨闆朵环閾佹椂搴斿敖閲忛€夌敤绾崇背闆朵环閾侊紝鍏惰緝澶х殑琛ㄩ潰绉兘浣垮弽搴旀洿蹇湴杩涜銆傝櫧鐒朵細鍑虹幇閽濆寲鐨勬儏鍐碉紝浣嗘€绘灄涓婄撼绫抽浂浠烽搧杈冮绮掔姸闆朵环閾佺殑鍌寲鎬ц兘鏇翠匠.闄や簡闆朵环閾佷互澶栵紝zn銆丗es銆丗eooh銆丗e304銆丮n00h銆丆u0绛夊潎琚姤閬撹兘淇冭繘杩囩~閰哥洂浜х敓路s04锛屾彁楂樺闅鹃檷瑙f湁鏈虹墿鐨勬哀鍖栨晥鑳姐€備竴鑸潵璇达紝鍚湁杩囨浮閲戝睘鐨勬哀鍖栫墿浣滀负鍌寲鍓傦紝姣斿崟绾娇鐢ㄨ繃娓¢噾灞炵瀛愮殑鎬ц兘鏇翠紭寮傘€侺ianghy绛夊湪闄嶈в瀵规隘鑻兒鐨勫疄楠屼腑鍙戠幇锛屼娇鐢ㄩ摐姘у寲鐗╁偓鍖栬繃纭吀鐩愮殑鏁堟灉瑕佸ソ浜庝娇鐢–u2 锛屾哀鍖栫墿褰㈠紡鐨勫偓鍖栧墏娲诲寲杩囩~閰哥洂鍏锋湁骞块様鐨勫彂灞曞墠鏅€?
4鍏朵粬娲诲寲鏂瑰紡
杩囩~閰哥洂鐨勬椿鍖栨柟寮忚繕鏈夋椿鎬х偔銆佺⒊绾崇背绠°€佸鍚堟椿鍖?濡傚弻閲戝睘銆佺传澶栧厜涓庤繃娓¢噾灞炶仈鍚堢瓑)绛夛紝涓旈兘鍙栧緱浜嗕笉閿欑殑鏁堟灉銆傝繎骞存潵锛岀偔鍩烘潗鏂欑敱浜庡弽搴旀潯浠舵俯鍜屻€佹棤浜屾姹℃煋绛変紭鐐癸紝鍙楀埌浜嗗箍娉涚殑鍏虫敞銆俌angsy绛夌爺绌跺彂鐜帮紝瀹ゆ俯涓嬪伓姘煋鏂橝07鑳藉湪娲绘€х偔琛ㄩ潰琚椿鍖栦骇鐢熺殑路s04鍜屼竴閮ㄥ垎路oh鏈夋晥鍘婚櫎銆傚悓鏍凤紝纰崇撼绫崇浣滀负娲诲寲鍓傦紝涔熻兘鏈夋晥鍘婚櫎a07136銆戙€傚弻閲戝睘娲诲寲鏄湪鍗曢噾灞炴椿鍖栫殑鍩虹涓婂彂灞曡€屾潵锛屾椿鍖栨晥鏋滄洿浣炽€傛缇庡绛?7銆戝湪鐮旂┒閾滈搧鍙岄噾灞炴椿鍖栬繃纭吀鐩愬幓闄ゆ按涓湁鏈烘薄鏌撶墿鐨勫疄楠屼腑鍙戠幇锛屼笌鍗曠函閾佷綔涓哄偓鍖栧墏鐩告瘮锛岄摐绂诲瓙鐨勬幒鏉傛彁楂樹簡瀵规薄鏌撶墿鐨勫惛闄勫拰鍌寲闄嶈в鐨勬€ц兘锛屽弽搴?0min鏃剁綏涓规槑b鐨勫幓闄ょ巼杈惧埌95%銆備负浜嗗寮烘椿鍖栨晥鑳斤紝鐮旂┒浜哄憳杩樺父灏嗗嚑绉嶆椿鍖栨柟娉曡仈鍚堥噰鐢紝濡傚垬鏅楃瓑鐢ㄧ传澶栧厜鍜岄浂浠烽搧鍏卞悓娲诲寲杩囩~閰哥洂鍘婚櫎鍏ㄦ盁杈涚兎纾洪吀鐩愶紝鍘婚櫎鐜囪揪鍒?1%銆備絾鏄湪鍑犵娲诲寲鏂规硶鑱旂敤鏃讹紝搴斿綋鍚屾椂鑰冭檻鍘婚櫎鏁堟灉鍜屾垚鏈棶棰樸€?
5鎬荤粨鍜屽睍鏈?br />
鐢变簬纭吀鏍硅嚜鐢卞熀鐨勬姉姘у寲鎬э紝杩囩~閰哥洂娲诲寲鎶€鏈湪鐜棰嗗煙鏂圭敩i鐨勫簲鐢ㄦ剤鍔犲箍娉涖€傚湪鐑椿鍖栥€佸厜娲诲寲鍜岃繃娓¢噾宕斿寲娲诲寲绛夋椿鍖栨柟寮忎腑锛岀儹娲诲寲鐨勮兘鑰楃浉瀵硅緝楂橈紝涓嶉€傚悎搴旂敤浜庡疄闄呭簾姘村鐞嗕腑鍏夋椿鍖栦腑鐨勭传澶栧厜娲诲寲涔熷瓨鍦ㄨ兘鑰楀拰绱鐏绋冲畾鎬х殑闂锛屾棩鍏夋椿鍖栨柟寮忛渶瑕佽繘涓€姝ユ帰绱㈢殑鏂版柟鍚戯紱杩囨浮閲戝睘娲诲寲鏂瑰紡鐩稿鏇村姞缁忔祹瀹炵敤锛屾湭鏉ラ渶瑕佽繘涓€姝ユ帰绱綆婧跺嚭銆併€佹潵婧愮畝渚裤€佹垚鏈綆銆佹椿鍖栨晥鐜囬珮鐨勮繃娓¢噾灞炴哀鍖栫墿浣滀负娲诲寲鍌寲鍓傦紝鍚屾椂搴旇€冨療鍦ㄥ疄闄呭簾姘村鐞嗚繍琛屼腑鐨勬椿鍖栨晥鏋溿€傜洰鍓嶏紝涓€浜涙柊鍨嬫椿鍖栧墏濡傜偔鍩烘潗鏂欑瓑涔熷彇寰椾簡涓嶉敊鐨勬晥鏋滐紝鏈潵杩樺簲鑷村姏浜庡姹傛晥鏋滄洿濂界殑鏂板瀷娲诲寲鏂规硶
鍙傝€冩枃鐚?
銆?銆戠帇宄帮紝楂樼骇姘у寲鎶€鏈湪鏈夋満搴熸按澶勭悊涓殑鐮旂┒杩涘睍銆怞銆戯紝骞夸笢鍖栧伐锛?016 (9) 190-191.
銆?銆?浠荤櫨绁ワ紝娈疯寕鐐紝鑼冩櫠鑾癸紝绛?杩囩~閰哥洂娲诲寲鎶€鏈幓闄ゆ按涓湁鏈烘薄鏌撶墿鐨勭爺绌惰繘灞昄jj.璧ゅ嘲瀛﹂櫌瀛︽姤鑷?br />
鐒剁増, 2016, 32( i 1) 34-37.
銆?銆戝垬妗傝姵锛屽瓩浜氬叏锛岄檰娲畤锛岀瓑锛屾椿鍖栬繃纭吀鐩愭妧鏈殑鐮旂┒杩涘睍[j銆戯紝宸ヤ笟姘村鐞嗭紝2012,32( 12) 6-10.
銆?銆?ji y f, dong c x, kong d y, et al. heat-activatedpersulfate oxidation of atrazine implications forremediation of groundwater cnnlaminalpd by herbicides[j]. chemical engineering journal, 2015, 263 45-54.
銆?銆戝紶钀嶈悕锛岃憶寤哄崕锛岄儹瀛︽稕锛岀瓑锛岀儹娲诲寲杩囩~閰哥洂闄嶈в鑱旇嫰鑳虹殑鐮旂┒銆怞]锛屾按澶勭悊鎶€鏈紝2016,42(3)65-68,75.
銆?銆慣an c q, gao n y, deng y, et al. degradation ofantipyrine by heat activated persulfatetj]. separation &
purification technology, 2013, 109(19) 122-128.
銆?銆戞牼娴峰浆锛岀儹娲诲寲杩囩~閰哥洂瀵圭幆澧冩縺绱犮€丳pcps绛夋湁鏈烘薄鏌撶墿鐨勯檷瑙g爺绌躲€怐銆戯紝鎵窞鎵窞澶у锛?015.
銆?銆戝粬浜戠嚂锛屽垬鍥藉己锛岃档鍔涳紝瀹跺埄鐢ㄧ儹娲诲寲杩囩~閰哥洂鎶€鏈幓闄ら樋鐗规媺娲ャ€怞銆戯紝鐜绉戝瀛︽姤锛?014,34(4)931
-937.
銆?銆戞潕鏃紵锛屽紶浜氾紝鐜嬪浗搴嗭紝绛夛紝鐑椿鍖栬繃纭吀鐩愰檷瑙f按浣撲腑姣掓铚便€怞銆戯紝鐜鍖栧锛?016,35( 10) 2089-2095.
銆?0銆?yang s y, wan 鍚?p, yang x, et at. a novel advancedoxidation process 1o degrade organic pollutantsinwastewatermicrowave-activated persulfate oxidationu]. journal of environmental sciences, 2009, 21 (9)1175-1180.
銆?1銆戠鎵块兘锛屽垬甯屾稕锛岄儜鏂囧锛屽井娉㈠姞鐑椿鍖栬繃纭吀鐩愰檷瑙f按涓簲绾ч厷鐨勭爺绌躲€怉銆戯紝鎸佷箙鎬ф湁鏈烘薄鏌撶墿璁哄潧鏆ㄧ涓冨眾鎸佷箙鎬ф湁鏈烘薄鏌撶墿鍏ㄥ浗瀛︽湳鐮旇浼氳鏂囬泦銆怌銆戯紝澶╂触锛?012.
銆?2銆?liang c j, su h w. identification of sulfate andhydroxyl radicals in thermally activated persulfate [ j ] 路industrial & engineering chemistry research, 2009, 483
銆?3銆?5558-5562.li s, gao n y, xing m y, et al. study on the removalof chlortetracycline in water through uv-activatedpersulfate process [ j ]. journal of harbin institute oftechnology,2016, 48(8) 96-101.
銆?4銆?matzek l w, carter k e. activated persulfate for organicchemical degradationa review[j]. chemosphere, 2016,151178-188.
銆?5銆?neppolian b, celik e, choi h. photochemical oxidationof arsenic ( m ) to arsenic ( v ) using peroxydisuuateions asanoxidizingagenttj]. environmental science &technology, 2008, 42
銆?6銆?6179-6184.ultraviolet activated persulfate oxidation of phenol [ j ] 路
chemosphere, 2011, 82(8) 1168-1172.
銆?7銆?gao y q, gao n y, deng y, et al. ultraviolet ( uv)light-activated persulfate oxidation of sulfamethazine inwatert j銆? chemicalengineering journal, 2012, ( 195-196) 248-253.
銆?8銆?dhaka s, kumar r, khan m a, et al. aqueous phasedegradation of methyl paraben using uv-activatedpersulfate method [ j ]. chemical engineering journal,2017, 321 1 1-19
銆?9銆戝瓩瀛愪负锛岄珮涔冧簯锛岀帇濂曞矚锛岀绱婵€娲昏繃纭吀鐩愰檷瑙f按涓隘闇夌礌鐨勭爺绌躲€怞銆戯紝涓浗缁欐按鎺掓按锛?015,31(21) 124-128.
銆?0銆? ghauch a, baalbaki a, amasha m, et al. contributionof persulfate in uv-254 nm activated systems forcomplete degradation of chloramphenicol antibiotic inwater l j ]. chemical engineering journal, 2017, 317 1012-1 025.
銆?1銆?1瀹嬫床銆佺传澶栧厜鍖栧姘у寲/杩樺師澶勭悊鍏ㄦ盁杈涢吀鐨勭爺绌躲€怐]锛屾姹夊崕涓鎶€澶у锛?014.
[22]鏈辨姹燂紝鏃ュ厜/fe锝?2 v杩囩~閰哥洂浣撶郴涓吀鎬у垰
鏋滅孩闄嶈в鐮旂┒銆孌]锛屽ぇ杩炲ぇ杩炴捣浜嬪ぇ瀛︼紝2012.
[23]瀛欏▉锛屽垬鏄ュ┓锛屾潕濞?閲戝睘绂诲瓙鍦ㄨ繃纭吀鐩愰檷瑙g敳鍩烘鏌撴枡搴熸按涓椿鍖栦綔鐢ㄧ殑姣旇緝鍒嗘瀽[j]锛岃窘瀹佸寲2014(11) 1 373-1 375.
[24]lzq noonguez o, rjillllub n, 1lvillc1v 11 ? uu w"priority and emerging pollutants with persulfate activatedby iron effect of iron valence and particle size[j] 路chemical engineering journal, 20 1 7, 3 1 8 1 97-205.
[ 25 ] oh s y, kang s g, chiu p c. degradation of 2, 4-dinitrotoluene bypersulfate activated with zero-valent iron
[ j ]. science of the total environment, 2010, 408 ( 16)3464-3468.
[26]钄℃稕锛屽紶鐠愬悏锛岃儭鍏睙锛岀瓑.闆朵环閾佹椿鍖栬繃浜岀~閰哥洂姘у寲闄嶈в闃跨壒鎷夋触銆怞]路搴旂敤鍖栧锛?013,30(1) 114涓€
[27]鍒樻櫁锛岃绉﹀潳锛岃寤虹孩銆佺传澶栧厜鍔╅浂浠烽搧娲诲寲杩囩~閰哥洂闄嶈в鍏ㄦ盁杈涚兎纾洪吀鐩愩€怞]锛岃タ鍗楃鎶€澶у瀛︽姤锛?017, 32(1) 20-24.
[28] ai-shamsi m a, thomson n r. treatment of organiccompounds by activated persuuate using nanoscalezerovalent imntj]. industrial & engineering chemistryresearch, 2013, 52(38)13 564-13 571.
[29] li y, li h, zhang j, et al. efficient degradation ofcongo red by sodium persulfate activated with zero-valent zincu]. water air & soil pollution, 2014, 225(9) 1-8.
[30] chen h, zhang z l, feng m, et al. degradation of 2,4-dichlorophenoxyacetic acid in water by persultateactivated with fes ( mackinaivite ) [ j ]. chemicalengineering journal, 2017, 313 498-507.
[31] jo y h, hong s h, park t j, et al. the synthesi zedand thermally modified mn-ca-feooh composite inpersulfate system lts role to discolor methylene blue[j]. applied surface science, 2014, 301 ( 10) 576-583.
[32] jafari a j,fenton-likefe304 as a heterogeneous persuuate activator adsorptionand degradation studies [j]. journal of industrial &engineering chemistry, 2017, 45323-333.
[33]鏉庨槼锛屛?mnooh鍜孋uo鍌寲杩囩~閰哥洂姘у偓鍖栬嫰閰氭満鍒剁殑鐮旂┒[d]锛屽ぉ娲ュぉ娲ュ伐涓氬ぇ瀛︼紝2016.
[34] liang h y, zhang y q, huang s b, et al. oxidativedegradation of p-chloroaniline by copper oxidateactivated persulfatetj]. chemical engineering journal,2013, 218(3) 384-391.
[35] yang s y, yang x, shao x t, et al. activated caboncatalyzed persulfate oxidation of azo dye acid orange 7 atambient temperature [ j ]. journal of hazardousmaterials, 201 1, 186( 1 ) 659-666kakavandi b, jaalinzadehc n, et al.rtalytic oxidation of tetracycline by ac@
2013, 218(3) 384-m
yang s y, yang x, shao x t, et al. activated carbotcatalyzed peisulfate oxidation of azo dye acid orange 7 aambient temperature [ j ]. journal of hazardou
materials, 201 1, 1 86 ( 1 ) 659-666.
[36]闄堝鏂岋紝榄忔垚鑰€锛屾埧鑱紝绛夈€佺⒊绾崇背绠℃椿鍖栬繃浜岀~閰稿皝闄嶈в鍋舵爱鏌撴枡閰告€ф7[j]路涓浗鐜绉戝锛?016,31(12) 3 618-3 624.
[37]娈电編濞燂紝椹倳鏂囷紝涓囬噾娉夛紝鍐㈠簲鐢ㄩ搧閾滃弻閲戝睘鏈夋満鎭囨灦娲诲寲杩囩~閰哥洂鍌寲鍓傚幓闄ゆ按涓湁鏈烘薄鏌撶墿鐨勭爺鎹嶽j]锛岀幆澧冪瀛﹀鎶ワ紝2017,37(5) 1 742-1750.
[38] -shamsi m a, thomson n r, forsey s p. iron baselbimetallic nanoparticles to activate peroxygens [ j ]chemical engineering journal, 2013, 232 ( 9 ) 555563.